What Kind of Acid, Base or Buffer Problem is It, Anyway?
1. Is it a strong acid or base?
a. Strong acid, use pH = -log [H3O+]
b. Strong base, use pOH = -log [OH-], then 14-pOH = pH
2. Is is a weak acid?
a. Is only the weak acid [HA] present? Then use Ka = x2/ [HA] with x = [H3O+] and pH = -log [H3O+] (ICE method)
b. Are both the weak acid and its conjugate
base present, or is this a buffer solution? Then use the
Henderson-Hasselbalch equation.
pH = pKa + log [A-]/[HA]
3. Is it a conjugate base? e.g. Sodium acetate, potassium formate etc
Use Kb = [HA][OH-]/[A-]==> Kb x Ka = 1 x 1014 ==> Kb = x2/[A-] with x = [OH-] and pOH = -log [OH-], then 14-pOH = pH
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