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CHEM
1110
Spring 2003
Chemical Kinetics
Additional Problem 2
The
hydrolysis of sucrose, in which a sucrose molecule is broken down into a glucose
molecule and a fructose molecule, is a part of the digestive process.
How strongly does the rate depend on the body temperature?
Calculate the rate constant for the hydrolysis of sucrose at 35oC,
given that k = 1.0 x 10-3 M-1 s-1 at 37oC
(normal body temperature), and the activation energy of the reaction is 108 kJ
mol-1. Ans. 7.6 x 10-4 M-1s-1
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